1-(4-Bromophenyl)ferrocene
نویسندگان
چکیده
In the title compound, [Fe(C(5)H(5))(C(11)H(8)Br)], the distance of the Fe atom from the centroids of the unsubstituted and substituted cyclo-penta-dienyl (Cp) rings is 1.644 (1) and 1.643 (1) Å, respectively. The ferrocenyl moiety deviates from an eclipsed geometry, with marginally tilted Cp rings and an inter-planar angle between the Cp and benzene rings of 13.0 (4)°. The crystal structure is stabilized by C-H⋯π inter-actions between a cyclo-penta-dienyl H atom and the cyclo-penta-dienyl ring of a neighbouring mol-ecule.
منابع مشابه
2-Amino-4-(4-bromophenyl)-6-ferrocenylpyridine-3-carbonitrile
The title compound, [Fe(C(5)H(5))(C(17)H(11)BrN(3))], was synthesized by the reaction of 4-bromo-benzaldehyde, acetyl-ferrocene and ammonium acetate in an aqueous medium. The crystal packing is stabilized by inter-molecular N-H⋯N hydrogen bonds. The dihedral angles between the phenyl ring and the pyridine and cyclopentadienyl rings are 51.67 (13) and 12.12 (21)°, respectively.
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